Berkeley Lab

Niobium-Tin Superconductors: Fabrication and Applications

Researchers at ATAP are producing niobium-tin cables to create more powerful superconducting magnets that could extend the capabilities of particle accelerators and realize the promise of fusion.

Ian Pong (right) and Andy Lin from ATAP wind superconducting wire into cables for new magnets for the High-Luminosity Large Hadron Collider Upgrade Project. (Credit: Marilyn Sargent/Berkeley Lab)

By Carl A. Williams, August 23, 2023

Particle accelerators and colliders have played a crucial role in advancing scientific research. They have led to significant discoveries in particle and high-energy physics, material science, medicine, and many other fields. They are also an enabling technology for new research areas like fusion.

Superconducting magnets are essential components of many modern accelerators; they shape and direct the particle beams and determine the energy reach of the accelerator. These magnets are fabricated using coils made from superconducting wires that convey electrical currents with virtually no resistance.

During operation, however, these coils must be cooled to extremely low temperatures (hundreds of degrees below freezing) and below their critical temperature (TC)—the temperature at which they become superconducting. Superconducting materials with a TC of about 20 K (-424 °F) are called low-temperature superconductors (LTS), while those with a TC of approximately 77 K (-321 °F) are referred to as high-temperature superconductors.

“While the Tc of a superconductor is important,” explains Ian Pong, a Staff Scientist from the Superconducting Magnet Program at Berkeley Lab’s Accelerator Technology & Applied Physics (ATAP) Division, “it is the current carrying capability at high magnetic fields and manufacturability that are the critical factors when choosing a material for making superconducting coils.”

He notes that because of their superior critical current density and ability to be manufactured cost-effectively, niobium-based superconductors—despite being LTS—dominate the superconductivity industry. “In particular, niobium-titanium (Nb-Ti) and niobium-three-tin (Nb3Sn) have become the materials of choice for making the cables used in superconducting magnets.” 

Pong was recently invited to author a chapter entitled “Processing of Low TC Conductors: The Compound Nb3Sn” for the second edition of the “Handbook of Superconductivity” (CRC Press, July 2022). The chapter describes the fabrication methods and design factors relating to Nb3Sn superconductors. He has extensive experience and expertise in working with Nb3Sn superconductors. For example, his doctoral studies—for which he won the Institute of Physics best Ph.D. thesis prize in Condensed Matter and Materials Physics in 2009—focused on developing Nb3Sn superconductors. After initially joining ATAP as a project scientist in 2013, Pong became the cable task leader for the Large Hadron Collider (LHC) Accelerator R&D Program, a U.S. Department of Energy-directed R&D program, and the High-Luminosity LHC Accelerator Upgrade Project (HL-LHC AUP). Before joining ATAP, he was a Monaco fellow at the International Thermonuclear Experimental Reactor (ITER), overseeing worldwide benchmarking efforts and monitoring the production of Nb-Ti and Nb3Sn, and before that, a postdoctoral fellow at CERN working on the advanced characterization of prototype Nb3Sn conductors for future accelerators.

Niobium-tin’s time to shine

Although Nb3Sn was discovered in 1954, seven years before Nb-Ti, the latter’s relative ease of production, greater availability, better ductility, and resilience led researchers to choose it over Nb3Sn. These properties have made Nb-Ti superconductors the “workhorse” of the superconducting magnet industry. They are used in particle accelerators and colliders, such as the Tevatron at Fermilab and the Large Hadron Collider (LHC) at CERN, the world’s largest and most powerful accelerator, the magnetic resonance imaging and nuclear magnetic resonance machines used extensively in medical diagnosis, and experimental fusion reactors.

However, Nb-Ti superconductors can only generate magnetic fields up to 9-10 tesla. So, upgrades to accelerators, like the HL-LHC AUP, which aims to extend the capabilities of the LHC and allow researchers to study phenomena in much greater detail, will require Nb3Sn superconductors because of their ability to generate much higher magnetic fields.

Performance requirements in different applications and the critical surfaces of Nb3Sn compared with Nb-Ti. (HEP = High Energy Physics, NMR = Nuclear Magnetic Resonance.) (Credit: modified version by Ian Pong reproduced with the permission of Arno Godeke)

“Not only do Nb3Sn wires have a critical magnetic field and critical temperature about twice that of Nb-Ti,” explains Pong, “they are also the closest material to Nb-Ti in production maturity and can be fabricated in mile-length strands in tonnage quantities.”

To date, the largest consumer of Nb3Sn superconductors is ITER. A global scientific partnership between 35 nations, ITER aims to produce a fusion reactor capable of replicating the processes that power the Sun. The technology promises a source of unlimited, carbon-free energy.

“The worldwide production of Nb3Sn before ITER was about 15 tonnes per year, and during the peak of ITER production, it was about 150 tonnes per year,” notes Pong. “ITER’s toroidal field and central solenoid superconducting magnets, which confine the plasma for fusion reactions, require more than 600 tonnes of Nb3Sn strands.”

He adds that the HL-LHC, which will be used for high-energy and particle physics research, is another primary consumer driving demand for Nb3Sn. The project, he says, will require about 30 tonnes of high-performance Nb3Sn strands for the accelerator’s upgrade magnets.

“This will be the first use of Nb3Sn in an accelerator and will enable much stronger magnetic fields to create beams with a higher luminosity that could break new ground, potentially leading to new discoveries in high energy and particle physics.”

Developing new generations of superconductors has been critical to progressively advancing the available magnetic fields, a focus of the U.S. Magnet Development Program led by Berkeley Lab.

Fabricating niobium-tin superconductors

According to Pong, three commonly used methods exist for fabricating Nb3Sn superconducting wires. These include the bronze method, where the tin source is copper-tin-bronze; the internal tin method, which uses pure tin; and the powder-in-tube process, in which the tin is in powder form.

“We typically use the internal tin method for applications requiring wires to carry a very high electrical current, like particle accelerators,” he says. “The bronze route conductor is typically used for lower-critical-current-density and low-loss applications.”

He notes that the application and the fabrication cost are “usually the main factors” in determining which method is employed.

Pong says that while these fabrication methods are effective in making Nb3Sn wire, designing and making superconducting cables from Nb3Sn wires “is still very challenging.”

“For example, whereas wires made from Nb-Ti are ready to use once drawn, Nb3Sn is as brittle as glass—so conventional wire fabrication techniques, such as extrusion, swaging, and drawing, cannot be used after it is formed.”

Because of this brittleness, he adds, Nb3Sn cannot withstand the cabling process. Consequently, the niobium and tin components are separated inside the wire, and the superconducting Nb3Sn compound is formed only after the final deformation occurs via reactive diffusion processes, typically after the coil winding step.

The strand cabling machine located at Berkeley Lab. (Credit: Ian Pong/Berkeley Lab)

To make Nb3Sn wires superconducting, the unreacted Nb3Sn wires or cables are heat-treated at about 1,200 °F to 1,300 °F over several days to form the superconducting compound before the final magnet assembly steps—which include coil impregnating with epoxy, coil assembly into a support structure, and pre-stressing of the complete magnet assembly to maintain compression throughout its operational regimes—are performed and the magnet is cooled down to liquid helium temperatures of 1.9 K to 4.2 K (-456 °F to -452 °F).

While Nb3Sn performs better than Nb-Ti, Pong says it is much more strain-sensitive. “Because of a thermal mismatch among the different components and the massive magnetic forces they experience during energization, the Nb3Sn superconductors are subjected to complex and intense stresses.”

The challenge, he says, is how to prevent a reduction in its performance from strain or other reasons. “For instance, the mechanical deformation from the cabling process should induce a negligible impact on the post-heat treatment thermal and electromagnetic performance of the Nb3Sn wires that comprise the coil.”

To achieve this, Pong and his team use a thread-winding machine at the cabling facility at Berkeley Lab. Here, they not only cable all the unreacted strands of Nb3Sn with controlled tension into a precise geometry but also monitor the product’s quality using state-of-the-art equipment to ensure there is no single defect across the entire cable length.

Commenting on the work, ATAP Division Director Cameron Geddes said: “Ian and all those involved have done an outstanding job in bringing a new higher performance material to applications like the HL-LHC-AUP upgrade, part of an inspiring progression in superconducting materials that are progressively extending the magnetic fields available and the science they enable.”


To learn more …

  1. Pong, I., Chapter E3.8 “Processing of Low Tc Conductors: The Compound Nb3Sn” in “Handbook of Superconductivity: Processing and Cryogenics,” Volume 2, 2nd Edition, CRC Press, July 2022, DOI:
  2. A Procedural Solution for Determining the Temperature Dependence of Nb3Sn Superconductor Performance
  3. Three National Labs Team Up for Accelerator Focusing-Magnet Record
  4. Cabling for High-Luminosity LHC Project Reaches Halfway Mark
  5. HL-LHC AUP Receives CD-3 Approval
  6. Cabling for LHC Upgrade Wraps Up


For more information on ATAP News articles, contact Carl A. Williams (